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Superposition State Molecular Dynamics
The ergodic sampling of rough energy landscapes is crucial for understanding phenomena like protein folding, peptide aggregation, polymer dynamics, and the glass transition. These rough energy landscapes are characterized by the presence of many local minima separated by high energy barriers, where Molecular Dynamics MD fails to satisfy ergodicity. To...
Ternary Complexes Comprising Polyphosphoramidate Gene Carriers With Different Types of Charge Groups Improve Transfection Efficiency
To understand the influence of charge groups on transfection mediated by polymer complexes, we have synthesized a series of biodegradable and cationic polyphosphoramidates PPAs with an identical backbone but different side chains. The mechanism of enhancement in transfection efficiency by the mixture carriers appears to be unrelated to the particle...
Thermodynamic Measurements and Predictions of the Adsorption of Short-Chain Peptides on Nanothin Polymer Films
This contribution describes experimental measurements of sub molecular-level interaction energies involved in the process of peptide adsorption on polymer films. The objective of this study was to use surface plasmon resonance SPR spectroscopy to measure the Gibbs energy change on adsorption Gad for pairs of various homopeptides on highly uniform,...
Polymer-Dispersed Bicontinuous Cubic Glycolipid Nanoparticles
The paper reveals that certain amphiphilic polymers such as PEO-PPO-PEO triblock copolymer PL can directly disperse a cubic glycolipid, 1-O-phytanyl--D-xyloside (-XP), into bicontinuous cubic nanoparticles in water medium. The use of synchrotron small-angle X-ray diffraction SSAXD permitted the identification of the exact structure of these dispersed particles in the colloidal...
Poly(ethylene oxide sulfide): New Poly(ethylene glycol) Derivatives Degradable in Reductive Conditions
Poly ethylene oxide sulfide PEOS, polymers consisting of an internal ethylene oxide oligomer and disulfide linkage, were synthesized and characterized. The degree of polymerization was dependent upon temperature, dimethyl sulfoxide condition, and monomer hydrophobicity. The stability of PEOS was measured by the size exclusion chromatography method after the incubation both...
Liquid-Liquid Equilibrium Data, Viscosities, and Densities of Aqueous Mixtures of Poly(propylene glycol) With Tri-sodium Citrate at 298.15 K
Aqueous two-phase systems, which are useful for the separation of biological products from the complex mixtures in which they are produced,1,2 can be made from aqueous solutions of two water-soluble polymers or a polymer and a salt. Poly ethylene glycol PEG is often used in this technique, and there are...
Mechanism of Optically Inscribed High-Efficiency Diffraction Gratings in Azo Polymer Films
According to this paper, both volume refractive index and surface profile diffraction gratings could be laser inscribed in azo polymer thin films. The mechanism for the high-efficiency photoinduced surface gratings appears to be isomerization driven mass transport, with grating depths of up to 1 m achievable with films of an...
In Situ Immobilization of Proteins and RGD Peptide on Polyurethane Surfaces via Poly(ethylene oxide) Coupling Polymers for Human Endothelial Cell Growth
This white paper reveals about the pre-SMA synthesis and PEU surface modification that were characterized using nuclear magnetic resonance spectroscopy (1H NMR), attenuated total reflection infrared spectroscopy (ATR-FTIR), and X-ray photoelectron spectroscopy XPS. The cell morphologies were investigated by optical inverted microscopy OIM and scanning electrical microscopy SEM. The gelatin-...
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
This white paper considers radical polymerization which may be considered a mature technology with millions of tons of vinyl based homo- and copolymers being produced annually. This perception of maturity is based on the fact that free radical polymerization is so widely used industrially and in research laboratories for the...
Additional Resources
"Global Challenges/Chemistry Solutions" Debuts With Focus on Drinking Water
An authority on the quality of drinkingwater today describes new challenges for consumers and municipal watersupply systems, including unexpected consequences of efforts to conservewater, in the first of a special series of podcasts from the AmericanChemical Society ACS, the world's largest scientific society. Marc Edwards, Ph.D., notes that reduced-flush toilets,...
Antiterrorism and homeland defense; polymers and materials
Antiterrorism and homeland defense; polymers and materials. Ed. by John G. Reynolds et al. American Chemical Society 2007 273 pages $145.00 Hardcover ACS symposium series; 980 UG447 The editors (of Lawrence Livermore...
Multiscale simulation methods for nanomaterials
Multiscale simulation methods for nanomaterials. Ed. by Richard B. Ross and Sanat S. Mohanty. Wiley-Interscience 2008 275 pages $125.00 Hardcover TK7874 Large Scale Molecular Dynamics, Nanoscale, and Mesoscale Modeling and Simulation: Bridging the Gap...
Polymers for biomedical applications
Polymers for biomedical applications. Ed. by Anil Mahapatro and Ankur S. Kulshrestha. American Chemical Society 2008 420 pages $145.00 Hardcover ACS symposium series; 977 R857 Amongst the many materials being considered for...
Polymer durability and radiation effects
Polymer durability and radiation effects. Ed. by Matthew C. Celina Rogber A. Assink. American Chemical Society 2008 366 pages $150.00 Hardcover ACS symposium series; 978 QD381 Twenty-seven papers from the December 2005...
Rational environmental management of agrochemicals; risk assessment, monitoring, and remedial action
Rational environmental management of agrochemicals; risk assessment, monitoring, and remedial action. Ed. by Ivan R. Kennedy, et al. American Chemical Society 2007 415 pages $160.00 Hardcover ACS symposium series; 966 QH545 Feeding...
Professor Richard N. Zare Presented with American Chemical Society George C. Pimentel Award
Rohm and Haas Sponsors Award for Outstanding Contributions to Chemical Education SPRING HOUSE, Pa. -- A pioneer in the field of laser chemistry, Richard N. Zare, PhD, chair of the chemistry department at Stanford University, received the 2008 George C. Pimentel Award in Chemistry Education from the American...
A Louisiana State University chemist, Barry Dellinger, has been awarded a $30,000 grant by the American Chemical Society for his work
A LOUISIANA STATE UNIVERSITY chemist, Barry Dellinger, has been awarded a $30,000 grant by the American Chemical Society for his work, which includes research in the formation of toxic combustion by-products, incineration of hazardous materials, combustion-generated nanoparticles and environmentally persistent free radicals...
Rubber Division gives paper awards.(Meetings)
The Best Paper Committee of the Rubber Division of the American Chemical Society announced the Best Paper and Symposium Awards from the 172nd Rubber Division Technical Meeting, held last October in Cleveland, OH. Awards were presented at the Division's Spring 173rd Technical Meeting, held last month...
Diluted Seawater Boosts Nutritional Content of Tomatoes
You can grow a healthier tomato by watering it with diluted seawater, a new study shows. In an experiment in which researchers grew cherry tomatoes in either freshwater or a diluted solution of 12 percent seawater, the salt-water tomatoes developed higher levels of vitamin C, vitamin E, dihydrolipoic acid and...
Chinese Ants Show Promise in Fighting Arthritis, Other Diseases
Substances found in a type of Chinese ant may provide anti-inflammatory and painkilling benefits against several diseases, a new report says. Chemists analyzing extracts from a Chinese medicinal ant, Polyrhacis lamellidens , found two polyketides, potent natural products that other studies have deemed as promising treatments for arthritis, bacterial...
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